An object of the present invention is to provide a charging roller (i) which includes a rubber member whose surface is subjected to a hardening treatment using a solvent containing at least an isocyanate compound and (ii) which can prevent leakage of an ionic conductive agent even if the charging roller is placed under conditions of high temperature and high humidity for a long time. The charging roller is made by forming a rubber layer on a metal core. The rubber layer is an epichlorohydrin based rubber base material to which an ionic conductive agent is added, the rubber layer being subjected to a surface treatment by applying a solution containing the isocyanate compound and heating it. This surface treatment is carried out under such conditions that a coefficient of dynamic friction at a contact portion between the rubber layer and a photoreceptor becomes 0.4 or less.