Invention Grant
- Patent Title: Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol
- Patent Title (中): 制备含有包含环丁二醇的聚酯的透明成型制品的方法
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Application No.: US11390812Application Date: 2006-03-28
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Publication No.: US07959836B2Publication Date: 2011-06-14
- Inventor: Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Emmett Dudley Crawford , David Scott Porter , Gary Wayne Connell , Marcus David Shelby
- Applicant: Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Emmett Dudley Crawford , David Scott Porter , Gary Wayne Connell , Marcus David Shelby
- Applicant Address: US TN Kingsport
- Assignee: Eastman Chemical Company
- Current Assignee: Eastman Chemical Company
- Current Assignee Address: US TN Kingsport
- Agent Jennifer R. Knight; Eric D. Middlemas; Bernard J. Graves, Jr.
- Main IPC: B29D22/00
- IPC: B29D22/00 ; B29D17/00 ; B65D23/00 ; C08L57/00 ; C08L77/00

Abstract:
Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze, and comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
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