Invention Grant
US07960484B2 Method for transitioning between ziegler-natta and metalocene catalysts in a bulk loop reactor for the production of polypropylene
有权
用于生产聚丙烯的本体环管反应器中的齐格勒 - 纳塔和茂金属催化剂之间的转化方法
- Patent Title: Method for transitioning between ziegler-natta and metalocene catalysts in a bulk loop reactor for the production of polypropylene
- Patent Title (中): 用于生产聚丙烯的本体环管反应器中的齐格勒 - 纳塔和茂金属催化剂之间的转化方法
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Application No.: US12018225Application Date: 2008-01-23
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Publication No.: US07960484B2Publication Date: 2011-06-14
- Inventor: Ronald Tharappel , Renaud Oreins , William Gauthier , David Attoe , Kevin McGovern , Michel Messiaen , David Rauscher , Kai Hortmann , Michel Daumerie
- Applicant: Ronald Tharappel , Renaud Oreins , William Gauthier , David Attoe , Kevin McGovern , Michel Messiaen , David Rauscher , Kai Hortmann , Michel Daumerie
- Applicant Address: US TX Houston
- Assignee: Fina Technology, Inc.
- Current Assignee: Fina Technology, Inc.
- Current Assignee Address: US TX Houston
- Agent Diane L. Kilpatrick-Lee
- Main IPC: C08F2/02
- IPC: C08F2/02 ; C08F4/42 ; C08F210/00

Abstract:
Polymerization processes in a bulk loop reactor are described herein. In particular, a method of contacting a flow of metallocene with a flow of propylene is provided. This method includes directing the flow of metallocene towards a junction, directing the flow of propylene towards the junction and maintaining a portion of the flow of metallocene separate from a portion of the flow propylene within a portion of the junction downstream of the flow of propylene into the junction. In another embodiment, a method of introducing a quantity of antifouling agent into a catalyst mixing system is provided. In this embodiment a portion of the antifouling agent is introduced at or downstream of a point of contact of a stream of propylene with a stream of catalyst. The antifouling agent may be a member, alone or in combination with other members, selected from Stadis 450 Conductivity Improver, Synperonic antifouling agent, and Pluronic antifouling agent.
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