Invention Grant
- Patent Title: Process for preparing secondary amides by carbonylation of a corresponding tertiary amine
- Patent Title (中): 通过羰基化相应叔胺制备仲酰胺的方法
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Application No.: US12416593Application Date: 2009-04-01
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Publication No.: US07960585B2Publication Date: 2011-06-14
- Inventor: Mondher Srasra , Pierre Jacobs , Bert Sels , Maria Christina Jacoba Tielen , Kristof Moonen , Peter Roose , Ivan Vanden Eynde
- Applicant: Mondher Srasra , Pierre Jacobs , Bert Sels , Maria Christina Jacoba Tielen , Kristof Moonen , Peter Roose , Ivan Vanden Eynde
- Applicant Address: BE Ghent
- Assignee: Taminco
- Current Assignee: Taminco
- Current Assignee Address: BE Ghent
- Agency: Sughrue Mion, PLLC
- Priority: EP08169717 20081121
- Main IPC: C07C231/10
- IPC: C07C231/10

Abstract:
The present invention relates to a process for preparing secondary amides with good selectivity by carbonylating a corresponding tertiary amine with carbon monoxide in a reaction mixture in the presence of a metal catalyst and in the presence of a halogen containing promoter. The metal catalyst comprises palladium. A same or even a much better catalytic activity can be obtained with palladium than with the much more expensive rhodium, especially when the palladium is used in a low concentration. Moreover, also a good selectivity can be achieved.
Public/Granted literature
- US20100130785A1 PROCESS FOR PREPARING SECONDARY AMIDES BY CARBONYLATION OF A CORRESPONDING TERTIARY AMINE Public/Granted day:2010-05-27
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