Invention Grant
- Patent Title: Hydrogenation product of block copolymer or sheet or film of the same
- Patent Title (中): 嵌段共聚物或片或其膜的氢化产物
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Application No.: US11887941Application Date: 2006-04-07
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Publication No.: US07985484B2Publication Date: 2011-07-26
- Inventor: Susumu Hoshi , Yukio Yamaura
- Applicant: Susumu Hoshi , Yukio Yamaura
- Applicant Address: JP Tokyo
- Assignee: Asahi Kasei Chemicals Corporation
- Current Assignee: Asahi Kasei Chemicals Corporation
- Current Assignee Address: JP Tokyo
- Agency: Finnegan, Henderson, Farbow, Garrett & Dunner, L.L.P.
- Priority: JPP.2005-110490 20050407
- International Application: PCT/JP2006/307490 WO 20060407
- International Announcement: WO2006/109743 WO 20061019
- Main IPC: B32B27/30
- IPC: B32B27/30 ; C08L53/02 ; C08F236/06

Abstract:
An object of the invention is to provide a block copolymer hydrogenation product suitable for a sheet and a heat shrinkable film which are excellent in solvent resistance, rigidity, elongation and transparency, which is excellent in a balance of physical properties such as solvent resistance, natural shrinkability, low-temperature shrinkability, rigidity, transparency and low-temperature elongation, and a composition thereof. The invention relates to a block copolymer hydrogenation product having a weight ratio of a vinyl aromatic hydrocarbon and a conjugated diene of 55/45 to 95/5, a number average molecular weight measured by gel permeation chromatography (GPC) of 30,000 to 500,000 and a hydrogenation rate of 30% or more, wherein the vinyl aromatic hydrocarbon incorporated into the hydrogenation product has a block rate of 60 to 98% by weight, wherein relative to the weight of the total vinyl aromatic hydrocarbon polymer blocks, the ratio of vinyl aromatic hydrocarbon polymer blocks having a molecular weight of 50,000 or less is 80% by weight or more and the ratio of vinyl aromatic hydrocarbon polymer blocks having a molecular weight of 15,000 or less is from 10 to 80% by weight, and wherein at least one peak temperature of function tan δ in a dynamic viscoelasticity measurement of the hydrogenation product is present within the range of exceeding −80° C. to lower than −10° C.
Public/Granted literature
- US20090061248A1 Hydrogenation Product of Block Copolymer or Sheet or Film of the Same Public/Granted day:2009-03-05
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