A matching system of an electronic device and a perpheral device and a matching method thereof are described. The system includes and electric device, having an identification mechanism for identifying a specific identification code and generating a control signal or a control instruction according to an identification result; and a peripheral device, electrically coupled to the electronic device selectively. The peripheral device includes an identification code unit for storing a group identification code; and a power control unit, for controlling an operation state of the peripheral device according to the control signal or the control instruction, when the peripheral device is electrically coupled to the electronic device. If the identification result is that the specific identification code is consistent with the group identification code, the power control unit controls the entire peripheral device to work normally according to the control signal or the control instruction.