An optical waveguide comprising a core and a clad characterized in that a desired part is heated and transited to machining strain release state, the part transited to the machining strain release state is curved with a specified bending radius and transited to machining strain state. That part of the optical waveguide is heated to a temperature within a range between the bending point and softening point and transited to machining strain state. The optical waveguide is an optical fiber having the outer diameter not shorter than 50 μm. The optical waveguide has the outer diameter not shorter than ten times of the mode field diameter of the optical waveguide. The optical waveguide has a bending radius of 5.0 mm or less and difference equivalent of refractive index &Dgr;1 between the core and clad falls within a range of 0.8-3.5%.