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US08017694B2 Efficient process of vulcanization of nonconjugated conductive polymers including rubbers 失效
包括橡胶在内的非共轭导电聚合物硫化的有效方法

Efficient process of vulcanization of nonconjugated conductive polymers including rubbers
Abstract:
Nonconjugated conductive polymers, which are all polymers that have a ratio of double bonds to total bonds of less than ½ are doped with iodine to produce compositions with unexpected characteristics in this invention. The mechanical and elastomeric properties of a nonconjugated polymer can be enhanced by doping the polymer with an electron acceptor such as iodine, in order to cure the polymer. Among the nonconjugated polymers are the cis-1,4-polyisoprene, cis-1,4 polybutadiene, styrene-butadiene copolymers (SBR), ethylene-propylene-diene monomer and poly (β-pinene). A heated mixture of iodine and sulfur produces a faster rate of vulcanization of rubber than using sulfur alone.
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