Invention Grant
US08017811B2 Hydroformylation process 有权
加氢甲酰化过程

  • Patent Title: Hydroformylation process
  • Patent Title (中): 加氢甲酰化过程
  • Application No.: US12600700
    Application Date: 2008-05-22
  • Publication No.: US08017811B2
    Publication Date: 2011-09-13
  • Inventor: Wilhelmus Peter Mul
  • Applicant: Wilhelmus Peter Mul
  • Applicant Address: US TX Houston
  • Assignee: Shell Oil Company
  • Current Assignee: Shell Oil Company
  • Current Assignee Address: US TX Houston
  • Priority: EP07108736 20070523
  • International Application: PCT/EP2008/056327 WO 20080522
  • International Announcement: WO2008/142143 WO 20081127
  • Main IPC: C07C45/50
  • IPC: C07C45/50
Hydroformylation process
Abstract:
A hydroformylation process for the production of alcohols comprising reacting, in a reactor system comprising one or more feed streams, a reaction environment and an output stream, a feedstock composition comprising a compound having at least one olefinic carbon-to-carbon bond with hydrogen and carbon monoxide in the presence of an organophosphine modified cobalt hydroformylation catalyst, wherein the hydroformylation process is carried out in the reaction environment, which comprises at least two reaction zones, wherein the at least two reaction zones comprise an earlier reaction zone and a later reaction zone, wherein the temperature of the later reaction zone is at a temperature which is at least 2° C. greater than the temperature in the earlier reaction zone, and the temperature of the later reaction zone is in the range of from 140° C. to 220° C., and the temperature of the earlier reaction zone is at least 130° C., wherein the molar ratio of hydrogen to carbon monoxide entering the earlier reaction zone is in the range of from 0.5 to 1.65, and wherein water is added into the reactor system.
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