Invention Grant
US08053542B2 Styrene-butadiene polymers with styrene gradient and methods of making the same
有权
具有苯乙烯梯度的苯乙烯 - 丁二烯聚合物和制备相同的方法
- Patent Title: Styrene-butadiene polymers with styrene gradient and methods of making the same
- Patent Title (中): 具有苯乙烯梯度的苯乙烯 - 丁二烯聚合物和制备相同的方法
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Application No.: US12989864Application Date: 2009-04-23
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Publication No.: US08053542B2Publication Date: 2011-11-08
- Inventor: Evemarie Hamann , Hagen Bartossek
- Applicant: Evemarie Hamann , Hagen Bartossek
- Applicant Address: CH Horgen
- Assignee: Styron Europe GmbH
- Current Assignee: Styron Europe GmbH
- Current Assignee Address: CH Horgen
- Agency: Brinks Hofer Gilson & Lione
- International Application: PCT/US2009/041483 WO 20090423
- International Announcement: WO2009/134665 WO 20091105
- Main IPC: C08F236/10
- IPC: C08F236/10 ; C08F2/06 ; C08F8/24 ; C08L9/06

Abstract:
The invention provides a process for polymerizing a polymer comprising monomeric units derived from styrene and 1,3-butadiene, said process comprising: A) adding less than 60 weight percent of the total amount of the butadiene used in the polymerization, to a reactor comprising the total amount of styrene used in the polymerization and solvent; B) adding at least one initiator to the reactor, and allowing the reaction to proceed for a time t; C) adding the remaining amount of butadiene to the reactor in two or more separate additions; and wherein for each butadiene addition, the amount of subsequent butadiene added is less than, or equal to, the amount of butadiene added in the immediately prior addition; and wherein for each butadiene addition, the butadiene is added over a time, tnc, and after each addition, the reaction is allowed to proceed for a time, tnr, wherein n is the number of the butadiene addition, and for each addition, n is independently greater than, or equal to, 1.
Public/Granted literature
- US20110178256A1 STYRENE-BUTADIENE POLYMERS WITH STYRENE GRADIENT AND METHODS OF MAKING THE SAME Public/Granted day:2011-07-21
Information query
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