Invention Grant
US08053613B2 Processes for producing 1,2,3,3,3-pentafluoropropene and precursors thereof 有权
制备1,2,3,3,3-五氟丙烯及其前体的方法

Processes for producing 1,2,3,3,3-pentafluoropropene and precursors thereof
Abstract:
A process is disclosed for making CH2ClCF2CClF2. The process involves reacting CH2ClF with CClF═CF2 in an addition reaction zone in the presence of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3−x, provided that the average values of x and y are not both 0. Also disclosed is a process for making CH2FCF2CF3 that involves reacting the CH2ClCF2CClF2 with HF in a fluorination reaction zone in the presence of a fluorination catalyst. Also disclosed is a process for making CHF═CFCF3 that involves dehydrofluorinating the CH2FCF2CF3.
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