Provided are a halogen-free electric wire including an insulation coating the life of which is less reduced in the case of the insulating coating being in contact with a PVC-resin-containing member; a wire bundle including the halogen-free electric wire and a PVC-resin-containing member, wherein a reduction in the life of a covering material of the halogen-free electric wire is lessened; and an automotive wiring harness comprising the wire bundle. The halogen-free electric wire includes a conductor and a covering material that covers the outer surface of the conductor, wherein the covering material includes a polyolefin resin and a flame retardant, and the flame retardant contains aluminum hydroxide as a main component, in particular, at a ratio of 80 weight percent or more. The wire bundle includes the halogen-free electric wires and a member containing a vinyl chloride resin. The automotive wiring harness comprises the wire bundle.