A wireless connection system and method are provided to connect diverse Ad-hoc network groups. A first Ad-hoc network group has a first network node and a first edge node wirelessly connecting with each other. The second Ad-hoc network group has a second network node and a second edge node wirelessly connecting with each other without connecting the first Ad-hoc network group. The first and second edge nodes have multiple wireless modules respectively. One of the wireless modules is used to connect wireless with other network nodes in the same Ad-hoc network group. The rest extra wireless module(s) is used to connect wirelessly with another extra wireless module(s) of the edge node(s) in different Ad-hoc network group(s). Therefore, the independent first and second Ad-hoc network groups are now capable of wirelessly connecting with each other.