A female hydraulic coupling member includes a bidirectional, pressure-energized probe seal for sealing between the body of the female coupling member and the cylindrical probe section of a male coupling member seated in the receiving chamber of the female member. In one embodiment, the pressure-energized seal comprises a first curved section which is oriented towards the external end of the receiving chamber in which it is installed and a second curved section oriented towards the interior end of the receiving chamber. The two curved sections are joined by a substantially straight back section. When the pressure of fluid within the coupling member is above the ambient fluid pressure, the first curved section is pressure-energized so as to increase its sealing effectiveness. When external pressure (e.g., the hydrostatic head) exceeds the pressure of fluid within the coupling member, the second curved section is pressure-energized so as to increase its sealing effectiveness. In another embodiment, the pressure-energized seal comprises a curved back section joining the first curved section and the second curved section. When the curved back section moves radially outward against a circumferential wall under the influence of fluid pressure within the seal, it effects a slight rotation of the first and second curved sections, thereby increasing their sealing effectiveness.