Invention Grant
- Patent Title: Method for producing butadiene from n-butane
- Patent Title (中): 从正丁烷生产丁二烯的方法
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Application No.: US11813935Application Date: 2006-01-16
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Publication No.: US08088962B2Publication Date: 2012-01-03
- Inventor: Catharina Klanner , Götz-Peter Schindler , Sven Crone , Frieder Borgmeier , Mark Duda , Falk Simon
- Applicant: Catharina Klanner , Götz-Peter Schindler , Sven Crone , Frieder Borgmeier , Mark Duda , Falk Simon
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Connolly Bove Lodge & Hutz LLP
- Priority: DE102005002127 20050117
- International Application: PCT/EP2006/050217 WO 20060116
- International Announcement: WO2006/075025 WO 20060720
- Main IPC: C07C5/333
- IPC: C07C5/333

Abstract:
A process for preparing butadiene, comprising A) providing a stream (a) comprising n-butane; B) feeding stream (a) comprising into at least one first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to obtain a stream (b) comprising n-butane, 1-butene, 2-butene, butadiene, hydrogen and low-boiling secondary constituents; C) feeding stream (b) and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating n-butane, 1-butene and 2-butene to obtain a stream (c) comprising n-butane, 2-butene, butadiene, low-boiling secondary constituents, carbon oxides and steam, wherein stream (c) has a higher content of butadiene than stream (b); D) removing the low-boiling secondary constituents and steam to obtain a stream (d) substantially consisting of n-butane, 2-butene and butadiene; E) separating stream (d) into a stream (e1) consisting substantially of n-butane and 2-butene and a stream (e2) consisting substantially of butadiene by extractive distillation; F) recycling stream (e1) into the first dehydrogenation zone.
Public/Granted literature
- US20080183024A1 Method for Producing Butadiene from N-Butane Public/Granted day:2008-07-31
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