A sequential control master-slave socket device includes at least one master socket, a plurality of slave socket, a plurality of switches, a load judgment device and a controller. Each master socket is coupled to an input power source. Inlet terminals of the switches are coupled to the input power source commonly and outlet terminals of the switches are respectively correspondingly coupled with the slave sockets for controlling whether the input power source is provided for each of the slave sockets. The load judgment device is coupled with each master socket for outputting a control signal according to an electrify state of a load connected with each master socket. The controller is coupled with the load judgment device and each switch to drive the switches one by one in a preset sequence under the control of the control signal.