A power supply system includes a power supply device, a switch device, a detecting device and a wireless operating terminal. The power supply device is connected to an electric appliance via the switch device to supply electric power to the electric appliance. The detecting device is connected to the switch device to detect working electric potential of the power supply device and the electric appliance, thereby generating and recording detecting data of the power supply device and the electric appliance. The wireless operating terminal communicates with the detecting device for remotely receiving the detecting data from the detecting device.