An electrical power generation system incorporates thermoelectric devices (TE Devices) for electrical power generation adjacent a flow path heat exchanger (HEX) adjacent to a vehicle flowpath structure such as a scramjet flow path to take advantage of the waste heat, high thermal gradients, and available, unused volume. A thermally conductive material communicates thermal energy from a vehicle external skin structure to the TE Device while a thermally conductive compliant material allows the TE Device to “float” with minimal mechanical stress.