Invention Grant
- Patent Title: Reactive distillation with olefin recycle
- Patent Title (中): 用烯烃回收反应蒸馏
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Application No.: US11988171Application Date: 2006-06-29
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Publication No.: US08148589B2Publication Date: 2012-04-03
- Inventor: Benjamin Patrick Gracey , Leslie William Bolton
- Applicant: Benjamin Patrick Gracey , Leslie William Bolton
- Applicant Address: GB Middlesex
- Assignee: BP Chemicals Limited
- Current Assignee: BP Chemicals Limited
- Current Assignee Address: GB Middlesex
- Agency: Nixon & Vanderhye
- Priority: EP05254238 20050706
- International Application: PCT/GB2006/002421 WO 20060629
- International Announcement: WO2007/003901 WO 20070111
- Main IPC: C07C11/02
- IPC: C07C11/02

Abstract:
Process for producing alkene(s) from a feedstock containing at least one monohydric aliphatic paraffinic primary (or secondary) alcohol(s), consisting of ethanol or propanol(s) or a mixture thereof. The process includes the steps of converting the monohydric aliphatic paraffinic primary (or secondary) alcohol(s) into the corresponding same carbon number alkene(s) in a reactive distillation column at elevated pressure and temperature so that the heads stream extracted from the top of the reactive distillation column comprises essentially the alkene(s), cooling the heads stream from the first step to a temperature sufficient to condense at least part of the alkene(s) with the highest boiling point, recycling at least part of the condensed alkene(s) from the second step back into the reactive distillation column, as a reflux return, and simultaneously recovering the remaining alkene(s).
Public/Granted literature
- US20090048474A1 Reactive distillation with olefin recycle Public/Granted day:2009-02-19
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