A network handover method applicable to network handover in ringing/ring back tone (RBT) or call hold is provided. According to this method, in ringing/RBT, one party performs a session negotiation with an Other End Point (OEP) via a call continuity application server, and then sends an off-hook signal to the OEP via the call continuity application server after the negotiation succeeds. Further, a call continuity application server and a user equipment (UE) are provided. According to the present disclosure, in ringing/RBT or call hold, even if the network coverage is not good, the UE may also be handed over to another network through call continuity, so as to effectively prevent the UE from dropping a call in ringing/RBT or call hold and thus improve the conversation quality of the user.