Invention Grant
US08168557B2 Method of restoring catalytic activity to a spent hydrotreating catalyst, the resulting restored catalyst, and a method of hydroprocessing
有权
对废加氢处理催化剂恢复催化活性的方法,所得到的还原催化剂和加氢处理方法
- Patent Title: Method of restoring catalytic activity to a spent hydrotreating catalyst, the resulting restored catalyst, and a method of hydroprocessing
- Patent Title (中): 对废加氢处理催化剂恢复催化活性的方法,所得到的还原催化剂和加氢处理方法
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Application No.: US12878825Application Date: 2010-09-09
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Publication No.: US08168557B2Publication Date: 2012-05-01
- Inventor: Josiane Marie-Rose Ginestra , James Dallas Seamans , Kenneth Scott Lee
- Applicant: Josiane Marie-Rose Ginestra , James Dallas Seamans , Kenneth Scott Lee
- Applicant Address: US TX Houston
- Assignee: Shell Oil Company
- Current Assignee: Shell Oil Company
- Current Assignee Address: US TX Houston
- Agent Charles W. Stewart
- Main IPC: B01J27/02
- IPC: B01J27/02 ; B01J27/047 ; B01J27/043 ; B01J23/00 ; B01J23/10 ; C10G17/00 ; C10G19/00 ; C10G21/00 ; C10G25/00 ; C10G27/00 ; C10G29/00 ; C10G31/00

Abstract:
A method of restoring catalytic activity to a spent hydroprocessing catalyst that has a first carbon concentration. The concentration of carbon on the spent hydroprocessing catalyst is reduced to provide a carbon-reduced catalyst having a second carbon concentration that is less than the first carbon concentration. The carbon-reduced catalyst is exposed to a solution, comprising a chelating agent and a solvent, for an aging time period sufficient to provide for a restored catalytic activity thereby resulting in an aged catalyst having incorporated therein the chelating agent and the solvent. The aged catalyst is exposed to conditions, including a drying temperature, so as to remove from the aged catalyst a portion of the solvent without removing a significant portion of the chelating agent from the aged catalyst thereby resulting in a dried aged catalyst. The dried aged catalyst is then sulfur treated to thereby provide a restored catalyst. The restored catalyst and those catalysts made by the treatment method can be used in a hydroprocessing process comprising contacting the restored catalyst with a hydrocarbon feedstock under hydroprocessing conditions.
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