Exemplary embodiments provide material compositions useful for electrophotographic devices and processes. The material composition can include a plurality of graphene-containing particles dispersed or distributed in a polymer matrix. Such material composition can be used for electrophotographic members and devices including, but not limited to, a fuser member, a fixing member, a pressure roller, and/or a release donor member. In one embodiment, a material composition dispersion can be applied on a substrate in electrophotography to form a functional member layer to control, e.g., to improve, at least one of thermal, mechanical and/or electrical properties.