An electrode assembly and a secondary battery having the same are provided. The electrode assembly includes a positive electrode including a positive electrode active material layer, a negative electrode including a negative electrode active material layer, and a porous layer for separating the positive and negative electrodes from each other that is formed of a combination of a ceramic material having a particle size of about 50 to 300 nm (particle size distribution value: D50) and a binder. Moreover, the porous layer contains an antacid. The secondary battery having the electrode assembly has satisfactory lifespan and overcharge characteristics.