Invention Grant
US08193287B2 Process for brominating butadiene copolymers by the addition of water or certain solvents 有权
通过加入水或某些溶剂来溴化丁二烯共聚物的方法

  • Patent Title: Process for brominating butadiene copolymers by the addition of water or certain solvents
  • Patent Title (中): 通过加入水或某些溶剂来溴化丁二烯共聚物的方法
  • Application No.: US12866992
    Application Date: 2009-02-25
  • Publication No.: US08193287B2
    Publication Date: 2012-06-05
  • Inventor: David B. Gorman
  • Applicant: David B. Gorman
  • Applicant Address: US MI Midland
  • Assignee: Dow Global Technologies LLC
  • Current Assignee: Dow Global Technologies LLC
  • Current Assignee Address: US MI Midland
  • Agency: Gary C Cohn PLLC
  • International Application: PCT/US2009/035046 WO 20090225
  • International Announcement: WO2009/139942 WO 20091119
  • Main IPC: C08F8/20
  • IPC: C08F8/20
Process for brominating butadiene copolymers by the addition of water or certain solvents
Abstract:
Butadiene copolymers are brominated using certain quaternary ammonium tribromides as the brominating agent. The bromination process proceeds easily under mild conditions, and produces a brominated product that has excellent thermal stability. A quaternary ammonium monobromide salt is produced as a reaction by-product. A solvent for the monobromide salt is added to the reaction after 25-90% bromination of the aliphatic carbon-carbon double bonds. This provides for significantly shorter reaction times while providing a product with few impurities.
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