Invention Grant
- Patent Title: Catalytic gas phase fluorination of 1233xf to 1234yf
- Patent Title (中): 催化气相氟化1233xf至1234yf
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Application No.: US12978241Application Date: 2010-12-23
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Publication No.: US08207383B2Publication Date: 2012-06-26
- Inventor: Dominique Deur-Bert , Laurent Wendlinger , Anne Pigamo
- Applicant: Dominique Deur-Bert , Laurent Wendlinger , Anne Pigamo
- Applicant Address: FR Colombes
- Assignee: Arkema France
- Current Assignee: Arkema France
- Current Assignee Address: FR Colombes
- Agency: Hunton & Williams, LLP
- Main IPC: C07C17/00
- IPC: C07C17/00

Abstract:
The present invention provides a process for preparing 1234yf, comprising: (i) contacting 1233xf with hydrogen fluoride HF in gas phase in the presence of a fluorination catalyst under conditions sufficient to produce a reaction mixture; (ii) separating the reaction mixture into a first stream comprising HCl, 1234yf and a second stream comprising HF, unreacted 1233xf and 245cb; (iii) recycling at least a part of the second stream at least in part back to step (i). The present invention also provides a process for preparing 1234yf, comprising: (i) contacting 1233xf with hydrogen fluoride HF in gas phase in the presence of a fluorination catalyst under conditions sufficient to produce a reaction mixture; (ii) separating the reaction mixture into HCl and a stream containing the fluorinated products; (iii) separating said stream containing the fluorinated products into a first stream comprising 1234yf and a second stream comprising HF, unreacted 1233xf and 245cb; (iv) recycling at least a part of the second stream at least in part back to step (i).
Public/Granted literature
- US20110319675A2 Catalytic Gas Phase Fluorination of 1233xf to 1234yf Public/Granted day:2011-12-29
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