A soil remediation system comprises an in-ground extraction well and separation apparatus connected to receive extracted soil vapors from the extraction well. The separation apparatus comprises plural pressure swing adsorption (PSA) components, respective ones of the PSA components containing a respective adsorption medium adapted to adsorb a respective species contained in the extracted soil vapors, the plural PSA components being connected in a serial succession to provide respective desorbed species flow streams of the respective species from the respective PSA components, some of the species being re-injected into the ground.