A light emitting/charge storage device is disclosed. The light emitting/charge storage device includes an organic light emitting diode (OLED) portion and at least one charge storage portion electrically and physically connected therewith. The OLED portion includes a first anode layer, a first cathode layer, and an electroluminescent layer disposed at least partially between the first anode layer and the first cathode layer. The at least one charge storage portion includes a second anode layer, a second cathode layer, and an ionic polymer dielectric layer disposed at least partially between the second anode layer and the second cathode layer, and/or a thin film battery layer. A light emitting/charge storage system is also disclosed. Certain embodiments of the device and system of the invention may provide integrated illumination and charge storage in a unitary stacked layered structure with flexible mechanical characteristics.