Invention Grant
- Patent Title: Method for continuously producing oxidized cyclic phenol sulfides
- Patent Title (中): 连续生产氧化型环状苯酚硫化物的方法
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Application No.: US12867207Application Date: 2009-02-16
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Publication No.: US08222428B2Publication Date: 2012-07-17
- Inventor: Masateru Yasumura , Yoshikazu Aoki , Masami Ito
- Applicant: Masateru Yasumura , Yoshikazu Aoki , Masami Ito
- Applicant Address: JP Tokyo
- Assignee: Hodogaya Chemical Co., Ltd.
- Current Assignee: Hodogaya Chemical Co., Ltd.
- Current Assignee Address: JP Tokyo
- Agency: Hoffmann & Baron, LLP
- Priority: JP2008-032671 20080214
- International Application: PCT/JP2009/052545 WO 20090216
- International Announcement: WO2009/102057 WO 20090820
- Main IPC: C07D341/00
- IPC: C07D341/00

Abstract:
The present invention discloses a method for continuously producing an oxidized cyclic phenol sulfide which comprises the continuous steps of reacting a para-alkyl phenol compound as a raw material with 1.7 to 2.5 molar equivalent of sulfur and 0.25 to 0.75 molar equivalent of an alkali metal reagent per 1 mol of the phenol compound (the first step); and oxidizing a cyclic phenol sulfide of the formula (2) produced by the above reaction with an oxidizing agent(s) in the same reactor as that of the first step and without taking the cyclic phenol sulfide out of the reactor: wherein R represents a straight or branched alkyl group having 1 to 6 carbon atoms, and m is an integer from 4 to 8, to obtain an oxidized cyclic phenol sulfide of the formula (3) (the second step): wherein R represents a straight or branched alkyl group having 1 to 6 carbon atoms, m is an integer from 4 to 8, and n is 1 or 2.
Public/Granted literature
- US20110028737A1 METHOD FOR CONTINUOUSLY PRODUCING OXIDIZED CYCLIC PHENOL SULFIDES Public/Granted day:2011-02-03
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