Systems, methods, and other embodiments associated with MRI excitation are described. One example method includes performing a calibration to determine a set of transmission parameters for a set of excitation pulses for transmission channels available on a multi-channel MRI transmitter. The set of excitation pulses are configured to produce a resulting nuclear magnetic resonance (NMR) signal from an object exposed to the set of excitation pulses. The resulting NMR signal comprises NMR signal associated with a first NMR resonance associated with the object and NMR signal associated with a second NMR resonance associated with the object.