Invention Grant
- Patent Title: Olefin oligomerization reaction processes exhibiting reduced fouling
- Patent Title (中): 烯烃低聚反应过程表现出减少的结垢
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Application No.: US13203590Application Date: 2009-03-27
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Publication No.: US08227653B2Publication Date: 2012-07-24
- Inventor: Michael W. Weber , James R. Lattner , Laughlin G. McCullough , Randell W. Dickey , Steven D. Brown , Peter N. Loezos
- Applicant: Michael W. Weber , James R. Lattner , Laughlin G. McCullough , Randell W. Dickey , Steven D. Brown , Peter N. Loezos
- Applicant Address: US TX Houston
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Houston
- International Application: PCT/US2009/038609 WO 20090327
- International Announcement: WO2010/110801 WO 20100930
- Main IPC: C07C2/08
- IPC: C07C2/08 ; C08F2/00 ; C08F210/02

Abstract:
The invention relates to olefin oligomerization methods and methods for reducing/inhibiting fouling in olefin oligomerization reactions comprising: contacting, in an oligomerization reactor (e.g., under oligomerization conditions), an alpha-olefin feed, a catalyst having an olefin selectivity of at least 90 mol % to a desired oligomerization product, a polymer anti-foulant, and optionally a diluent; selectively producing an effluent comprising the desired oligomerization product, unreacted olefin, and alpha-olefin-based polymer byproduct that causes fouling. The amount of polymer anti-foulant can be chosen to limit fouling to ≦20 g/kg desired oligomerization product, to remediate ≧3 grams fouled polymer/kg desired oligomerization product, and/or to reduce/inhibit polymer fouling by ≧10% over a selective oligomerization with substantially no added polymer anti-foulant. Advantageously, desired oligomerization product so obtained can also be polymerized/copolymerized with an alpha-olefin such as ethylene.
Public/Granted literature
- US20120016097A1 Olefin Oligomerization Reaction Processes Exhibiting Reduced Fouling Public/Granted day:2012-01-19
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