Invention Grant
- Patent Title: Solid state polymerization process for polyester with phosphinic acid compounds
- Patent Title (中): 具有次膦酸化合物的聚酯的固态聚合方法
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Application No.: US13214751Application Date: 2011-08-22
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Publication No.: US08258253B2Publication Date: 2012-09-04
- Inventor: Paul Odorisio , Stephen M. Andrews , Thomas F. Thompson , Si Wu , Paragkumar Thanki , Deepak M. Rane , Delina Joseph , Jianzhao Wang
- Applicant: Paul Odorisio , Stephen M. Andrews , Thomas F. Thompson , Si Wu , Paragkumar Thanki , Deepak M. Rane , Delina Joseph , Jianzhao Wang
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agent Tyler A. Stevenson
- Main IPC: C08G63/02
- IPC: C08G63/02 ; C08G64/00

Abstract:
Disclosed is a method for increasing the solid state polymerization (SSP) rates of metal catalyzed polyesters. The method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester and in a third step, further increasing the molecular weight and viscosity of the polyester under SSP conditions of a suitable temperature and pressure, where a metal catalyst is added in the first step or in the second step as a reaction catalyst, and where a certain phosphinic acid compound is added in the first step, in the second step or just prior to the third step. The polyester product exhibits low aldehyde formation during melt processing steps as well as excellent color.
Public/Granted literature
- US20110306710A1 Solid State Polymerization Process for Polyester with Phosphinic Acid Compounds Public/Granted day:2011-12-15
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