Polarization multiplexing with different differential phase shift keying (DPSK) schemes generally uses DPSK modulated signals modulated using different DPSK modulation schemes and combined with orthogonal polarizations relative to each other. The different DPSK modulation schemes may use different DPSK phase shifts to represent data, such as a regular DPSK modulation scheme and a π/2 DPSK modulation scheme. By using different DPSK modulation schemes to represent data on the orthogonally polarized signals, the DPSK demodulators may effectively separate the orthogonally polarized signals using the property of the DPSK receivers. To optimize performance, the DPSK modulated signals may also be bit-interleaved when combined with orthogonal polarization.