Invention Grant
US08278237B2 Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds
有权
用于低级烃芳构化的催化剂和用于生产芳族化合物的方法
- Patent Title: Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds
- Patent Title (中): 用于低级烃芳构化的催化剂和用于生产芳族化合物的方法
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Application No.: US12524029Application Date: 2008-02-13
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Publication No.: US08278237B2Publication Date: 2012-10-02
- Inventor: Shinichi Yamada , Tomohiro Yamada , Yuji Ogawa , Hirokazu Akiyama , Takuya Hatagishi
- Applicant: Shinichi Yamada , Tomohiro Yamada , Yuji Ogawa , Hirokazu Akiyama , Takuya Hatagishi
- Applicant Address: JP Tokyo
- Assignee: Meidensha Corporation
- Current Assignee: Meidensha Corporation
- Current Assignee Address: JP Tokyo
- Agency: Foley & Lardner LLP
- Priority: JP2007-073470 20070320; JP2007-293010 20071112; JP2007-293011 20071112
- International Application: PCT/JP2008/052284 WO 20080213
- International Announcement: WO2008/114550 WO 20080925
- Main IPC: B01J29/06
- IPC: B01J29/06 ; C07C2/52 ; C07C15/00

Abstract:
A catalyst for producing aromatic compounds from lower hydrocarbons while improving activity life stability of methane conversion rate; benzene formation rate; naphthalene formation rate; and total formation rate of benzene, toluene and xylene is formed by loading molybdenum and copper on metallo-silicate serving as a substrate and then calcining the metallo-silicate. When the catalyst is reacted with a reaction gas containing lower hydrocarbons and carbonic acid gas, aromatic compounds are produced. In order to obtain the catalyst, it is preferable that molybdenum and copper are loaded on zeolite formed of metallo-silicate after the zeolite is treated with a silane compound larger than a pore of the zeolite in diameter and having an amino group and a straight-chain hydrocarbon group, the amino group being able to selectively react with the zeolite at a Bronsted acid point of the zeolite. It is preferable that a loaded amount of molybdenum is within a range of from 2 to 12 wt. % based on total amount of the calcined catalyst while copper is loaded at a copper to molybdenum molar ratio of 0.01 to 0.8.
Public/Granted literature
- US20100016647A1 CATALYST FOR AROMATIZATION OF LOWER HYDROCARBONS AND PROCESS FOR PRODUCTION OF AROMATIC COMPOUNDS Public/Granted day:2010-01-21
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