An engine control system comprises an actuator control module and a tertiary injection module. The actuator control module provides secondary air to an exhaust system when a catalyst light-off mode is enabled and provides first and second injections of fuel to a cylinder during each engine cycle while the catalyst light-off mode is enabled. The tertiary injection module selectively provides a third injection of fuel to the cylinder during an exhaust phase of each engine cycle while the catalyst light-off mode is enabled. The first, second, and third injections are each separated by a period of time.