A coated optical fiber of the present invention comprises a glass fiber coated by at least two coating layers (a soft layer and a hard layer), wherein the glass surface of the glass fiber, where the at least two coating layers of the optical fiber are removed, has a peak intensity ratio of 0.6 or more in C3H7O+ (m/z 59) or C4H9O+ (m/z 73) with respect to Si+ (m/z 28) peak in cation analysis of TOF-SIMS. The optical fiber suppresses increase in its transmission loss even when it is exposed to a high-humidity environment or immersed in water.