To provide a glass substrate with protective glass which suppresses formation of microscopic scratches on the back surface of the glass substrate in the production process for a display device, and which prevents a strength decrease in the process or formation of etch pits after a chemical etching treatment; a process for producing a display device by using the glass substrate with protective glass; and silicone for release paper for the glass substrate with protective glass. A glass substrate with protective glass, which comprises a glass substrate and a protective glass substrate laminated on each other, and which is characterized in that the glass substrate and the protective glass substrate are laminated by a resin layer having removability.