Disclosed is a phthalocyanine compound characterized by being represented by the formula (1) below. This phthalocyanine compound has good affinity to titania, and is suitably used for an organic thin film of an organic solar cell and the like. [In the formula, M represents a hydrogen atom or a central metal; Z1 and Z2 independently represent a hydroxy group, an alkoxy group having 1 to 18 carbon atoms or a phenyl group; and Ar represents at least one aryl group selected from those represented by the following formulae (2) to (12). (In the formulae (2) to (12), R1 to R103 independently represent a hydrogen atom, a halogen atom, a hydroxy group, an amino group, a silanol group, a thiol group, a carboxyl group, a phosphoric acid group, a phosphate group, an ester group, a thioester group, an amide group, a nitro group, a monovalent hydrocarbon group, an organoxy group, an organoamino group, an organosilyl group, an organothio group, an acyl group or a sulfone group.)]