Invention Grant
US08344079B2 Molar ratio modifications to larger polyolefin catalysts 有权
对较大的聚烯烃催化剂的摩尔比改性

  • Patent Title: Molar ratio modifications to larger polyolefin catalysts
  • Patent Title (中): 对较大的聚烯烃催化剂的摩尔比改性
  • Application No.: US11967815
    Application Date: 2007-12-31
  • Publication No.: US08344079B2
    Publication Date: 2013-01-01
  • Inventor: Michael D. Spencer
  • Applicant: Michael D. Spencer
  • Applicant Address: US NJ Florham Park
  • Assignee: BASF Corporation
  • Current Assignee: BASF Corporation
  • Current Assignee Address: US NJ Florham Park
  • Agent Bernard Lau
  • Main IPC: C08F4/50
  • IPC: C08F4/50
Molar ratio modifications to larger polyolefin catalysts
Abstract:
Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of an olefin containing a solid titanium catalyst component having a substantially spherical shape and containing an internal electron donor, a support made by contacting substantially equal molar amounts of a magnesium compound and an epoxy compound in the presence of an aprotic solvent and subsequent treatment with a halogenating agent to provide a magnesium based catalyst support. The catalyst system can further contain an organoaluminum compound and an organosilicon compound. Also disclosed are methods of polymerizing or copolymerizing an alpha-olefin. The methods involve contacting an olefin with a catalyst system containing the solid titanium catalyst component.
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