The method for Hammerstein modeling of a steam generator plant includes modeling of the linear dynamic part of a Hammerstein model with a state-space model, and modeling the nonlinear part of the Hammerstein model with a radial basis function neural network (RBFNN). Particle swarm optimization (PSO), typically known for its heuristic search capabilities, is used for estimating the parameters of the RBFNN. Parameters of the linear part are estimated using a numerical algorithm for subspace state-space system identification (N4SID).