A method and apparatus is provided for efficiently searching and navigating XML data stored in a relational database. When storing a collection of XML documents, certain scalar elements may be shredded and stored in a relational table, whereas unstructured data may be stored as a CLOB or BLOB column. The approach includes identifying a reference address to within an XML tree index entry and storing the address in an xmltable index. The tree index entry allows for navigation in all axes. A path-based expression may be evaluated in the context of the reference address of the LOB. The result of the evaluation identifies another XML tree index entry containing a LOB locator used to retrieve the content from the document. The tree index, node index, and secondary function indexes are used together to enhance the performance of querying the XML data.