The invention is a method of phase separation in liquid mixtures comprising two or more components. The method comprises the steps of inserting the liquid mixture between suitably shaped and positioned electrodes and applying a voltage to the electrodes in order to produce a non-uniform electric field between the electrodes. The phase separation takes place with essentially all electrode geometries and the phase separation is reversible. The method is characterized in that the liquid mixture must contain dissociated positive or negative ions. In this case the phase separation takes place when the applied voltage is a few volts or less and when the temperature is many degrees above the binodal (coexistence) temperature Tc. The invention has many practical applications including: electrical field controlled lubrication, influencing the kinetics and spatial dependence of chemical reactions in liquid environments, controlling the propagation of light, and controlling the opacity of a window.