Invention Grant
US08367851B2 Hydroxymethylfurfural reduction methods and methods of producing furandimethanol
有权
羟甲基糠醛还原方法和生产呋喃二甲醇的方法
- Patent Title: Hydroxymethylfurfural reduction methods and methods of producing furandimethanol
- Patent Title (中): 羟甲基糠醛还原方法和生产呋喃二甲醇的方法
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Application No.: US13173942Application Date: 2011-06-30
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Publication No.: US08367851B2Publication Date: 2013-02-05
- Inventor: Michael A. Lilga , Richard T. Hallen , James F. White , Michel J. Gray
- Applicant: Michael A. Lilga , Richard T. Hallen , James F. White , Michel J. Gray
- Applicant Address: US WA Richland
- Assignee: Battelle Memorial Institute
- Current Assignee: Battelle Memorial Institute
- Current Assignee Address: US WA Richland
- Agency: Wells St. John P.S.
- Main IPC: C07D307/02
- IPC: C07D307/02

Abstract:
A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
Public/Granted literature
- US20110306780A1 Hydroxymethylfurfural Reduction Methods and Methods of Producing Furandimethanol Public/Granted day:2011-12-15
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