Invention Grant
- Patent Title: Use of chemical reaction to separate ethylene from ethane in ethane-based processes to produce acetic acid
- Patent Title (中): 使用化学反应将乙烯从乙烷中分离出来,生成乙酸
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Application No.: US12223222Application Date: 2007-01-30
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Publication No.: US08383854B2Publication Date: 2013-02-26
- Inventor: Debra Ann Ryan , James A. Foster
- Applicant: Debra Ann Ryan , James A. Foster
- Applicant Address: US TX Irving
- Assignee: Celanese International Corp.
- Current Assignee: Celanese International Corp.
- Current Assignee Address: US TX Irving
- Agent Michael W. Ferrell
- International Application: PCT/US2007/002350 WO 20070130
- International Announcement: WO2007/092189 WO 20070816
- Main IPC: C07C51/16
- IPC: C07C51/16

Abstract:
Described herein is a process in which acetic acid is produced by ethane oxidation. One byproduct of the ethane oxidation is ethylene. High ethylene content in the recycle gas stream will lead to poor efficiencies and higher losses to the COx byproduct in the acetic acid reactor. In fact, ethylene in the recycle feed competes with the ethane for the limited amount of oxygen feed, resulting in higher inefficiencies to carbon oxides than straight ethane oxidation. Ethylene is removed in this process by a further oxidation reaction at a temperature low enough such that ethane is not reactive, but the ethylene is converted to acetic acid. Either the ethane oxidation reactor effluent or a portion or all of the recycle stream to the ethane oxidation reactor, or any combination of the same, can be processed in this manner to reduce the ethylene content of those streams.
Public/Granted literature
- US20110009667A1 Use of Chemical Reaction to Separate Ethylene FromEthane in Ethane-Base Processes to Produce Acetic Acid Public/Granted day:2011-01-13
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