Invention Grant
- Patent Title: Deoxygenation of fatty acids for preparation of hydrocarbons
- Patent Title (中): 用于制备碳氢化合物的脂肪酸脱氧
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Application No.: US13620268Application Date: 2012-09-14
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Publication No.: US08388829B2Publication Date: 2013-03-05
- Inventor: Richard T. Hallen , Karl O. Albrecht , Heather M. Brown , James F. White
- Applicant: Richard T. Hallen , Karl O. Albrecht , Heather M. Brown , James F. White
- Applicant Address: US WA Richland
- Assignee: Battelle Memorial Institute
- Current Assignee: Battelle Memorial Institute
- Current Assignee Address: US WA Richland
- Agency: Klarquist Sparkman, LLP
- Main IPC: C10M101/00
- IPC: C10M101/00 ; C10M177/00 ; C10G71/00

Abstract:
Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
Public/Granted literature
- US20130008080A1 DEOXYGENATION OF FATTY ACIDS FOR PREPARATION OF HYDROCARBONS Public/Granted day:2013-01-10
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