Biodegradable nanopolymer compositions and methods of making the compositions are provided. In a general embodiment, the present disclosure provides a biodegradable nanopolymer composition made from starting material comprising poly(lactic acid), co-polyester polymer with adipic acid compounded and nanoparticles of a mineral material such as silica and magnesium silicate. In addition, the present disclosure provides processes for making the biodegradable nanopolymer compositions as well as biodegradable articles made using the biodegradable nanopolymer compositions such as molded, formed and extruded articles.