Invention Grant
- Patent Title: Initiation system for the anionic polymerization of conjugated dienes, and method for preparing diene elastomers
- Patent Title (中): 共轭二烯的阴离子聚合引发体系和二烯弹性体的制备方法
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Application No.: US13139757Application Date: 2009-12-22
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Publication No.: US08394903B2Publication Date: 2013-03-12
- Inventor: Jean-Marc Marechal
- Applicant: Jean-Marc Marechal
- Applicant Address: FR Clermont-Ferrand CH Granges Paccot
- Assignee: Compagnie Generale des Etablissements Michelin,Michelin Recherche et Technique S.A.
- Current Assignee: Compagnie Generale des Etablissements Michelin,Michelin Recherche et Technique S.A.
- Current Assignee Address: FR Clermont-Ferrand CH Granges Paccot
- Agency: Buchanan Ingersoll & Rooney PC
- Priority: FR0858988 20081223
- International Application: PCT/EP2009/067747 WO 20091222
- International Announcement: WO2010/072761 WO 20100701
- Main IPC: C08F4/44
- IPC: C08F4/44 ; C08F12/02 ; C08F36/00 ; B01J31/00 ; C08C19/00

Abstract:
The present invention relates to a novel initiating system for the preparation of a living diene elastomer functionalized at the chain end by an amine group by anionic polymerization. The novel initiating system comprises an organolithium compound and a tin amide.The invention also relates to processes for the preparation of modified elastomers comprising an amine group at the chain end. These modified elastomers prove to be particularly advantageous in reinforced rubber compositions for tyres as they confer improved dynamic and mechanical properties in the vulcanized state.
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