A method and apparatus for video call connection in a dual standby mobile communication system are provided. A method for video call connection in a dual standby mobile communication terminal including a dual Subscriber Identity Module (SIM) card includes, when a paging signal requesting a video call is received from a network, identifying a system in which a first SIM card corresponding to the video call is camping, and, when the first SIM card is camping in a 2nd Generation (2G) system, identifying a system in which a second SIM card is camping, and, when the second SIM card is camping in a 3rd Generation (3G) system, requesting the network to forward the video call to the second SIM card.