An exhaust gas purifying system for a diesel engine has an ECU, a passage of exhaust gas, a unit having SCR catalyst, a NOx sensor placed at a downstream side of the unit, and a urea water adding valve placed at an upstream side of the unit. The SCR catalyst in the unit selectively adsorbs ammonia, and selectively purifies NOx contained in an exhaust gas emitted from the diesel engine by the adsorbed ammonia. The ECU changes the urea water adding amount, and performs abnormality diagnosis based on the detection result of the NOx sensor while changing an adding amount of the urea water. The ECU uses a first condition to indicate the presence of an excess NOx amount in the exhaust gas, and a second condition to indicate there is no error cause by the ammonia adsorption on the SCR catalyst.