Invention Grant
US08426640B2 Method for producing acrylic acid, and method for producing hydrophilic resin and method for producing water-absorbing resin using production method thereof 有权
制造丙烯酸的方法,以及亲水性树脂的制造方法以及使用其制造方法制造吸水性树脂的方法

  • Patent Title: Method for producing acrylic acid, and method for producing hydrophilic resin and method for producing water-absorbing resin using production method thereof
  • Patent Title (中): 制造丙烯酸的方法,以及亲水性树脂的制造方法以及使用其制造方法制造吸水性树脂的方法
  • Application No.: US12989553
    Application Date: 2009-04-24
  • Publication No.: US08426640B2
    Publication Date: 2013-04-23
  • Inventor: Kazuhiko SakamotoMasaru Ishikawa
  • Applicant: Kazuhiko SakamotoMasaru Ishikawa
  • Applicant Address: JP Osakak
  • Assignee: Nippon Shokubai Co., Ltd.
  • Current Assignee: Nippon Shokubai Co., Ltd.
  • Current Assignee Address: JP Osakak
  • Agency: Occhiuti Rohlicek & Tsao LLP
  • Priority: JP2008-116504 20080427
  • International Application: PCT/JP2009/058147 WO 20090424
  • International Announcement: WO2009/133813 WO 20091105
  • Main IPC: C07C51/42
  • IPC: C07C51/42 C08F20/06
Method for producing acrylic acid, and method for producing hydrophilic resin and method for producing water-absorbing resin using production method thereof
Abstract:
[Problem]There is provided, in a process for producing acrylic acid having a catalytic gas-phase oxidation reaction step, a condensation step, a collection step, a distillation step, a crystallization step, an acrylic acid recovering step or the like, a production method for acrylic acid, in which contamination of acrylic acid with protoanemonin without providing any additional purification treatment to the resultant purified acrylic acid can be reduced.[Solution]The problems described above can be solved by providing the production method for acrylic acid comprising A) a step obtaining an acrylic acid-containing gas by a catalytic gas-phase oxidation reaction of gas containing a acrylic acid raw material; B) a step of obtaining the acrylic acid-containing solution by introducing the acrylic acid-containing gas to the collection column or the condensation column and performing collection or condensation; C) a step of obtaining the crude acrylic acid by introducing the acrylic acid-containing solution to the distillation column or the crystallizer and performing distillation or crystallization, wherein a step of heat treating the acrylic acid-containing solution or the crude acrylic acid containing 100 ppm by mass or more of protoanemonin, under the condition of 100° C. or more of temperature, 1 hour or more of time and a step of introducing the heat-treated acrylic acid-containing solution or the crude acrylic acid to the collection column, the condensation column, the distillation column or the crystallizer, are included.
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