An optical fiber communication method for communication between a transmitting terminal and a receiving terminal includes the steps of: providing an optical fiber to be coupled to the transmitting terminal and including a core that is provided with at least one second-order Bragg grating structure and a cladding that surrounds the core; configuring the transmitting terminal to output a data-carrying optical signal to one end of the core of the optical fiber for subsequent wireless transmission of the data-carrying optical signal via radiation through the second-order Bragg grating structure of the optical fiber; and configuring the receiving terminal to receive the signal radiated by the second-order Bragg grating structure of the optical fiber. A transmitting device is also disclosed.